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Question

Chemistry Question on Acids and Bases

The pHpH of a solution obtained by mixing of 100mL100\, mL of a HClHCl solution of pH=2pH = 2 with 400mL400\, mL of another HClHCl solution of pH=3pH = 3 will be

A

2

B

3

C

2.5

D

2.8

Answer

2.5

Explanation

Solution

The correct answer is option (C): 2.5
100mL100\, mL of a HClHCl solution of pH=2p H=2
[H+]=102400mL\Rightarrow\left[H^{+}\right]=10^{-2} 400\, mL of a HClHCl
solution of pH=3pH=3 [H+]=103\Rightarrow\left[H^{+}\right]=10^{-3}
Resulting [H+]=100×102+400×103500\left[H^{+}\right]=\frac{100 \times 10^{-2}+400 \times 10^{-3}}{500} =1+0.4500=\frac{1+0.4}{500}
=1.4500=0.0028=\frac{1.4}{500}=0.0028
pH=log[H+]pH=log(0.0028)\because p H=-\log \left[H^{+}\right] \therefore p H=-\log (0.0028)
=2.5=2.5