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Question

Chemistry Question on Acids and Bases

The pH of a 0.02M NH4ClNH_4Cl solution will be [given Kb(NH4OH)=105K_b(NH_4OH) = 10^{-5} and log2=0.301]

A

4.65

B

5.35

C

4.35

D

2.65

Answer

5.35

Explanation

Solution

For the salt of strong acid and weak base
H+=KW×CKbH^{+} = \sqrt{\frac{K_{W} \times C}{K_{b}}}
[H+]=1014×2×102105\left[H^{+}\right] = \sqrt{\frac{10^{-14} \times2 \times10^{-2}}{10^{-5}} }
log[H+]=612log20- \log \left[H^{+}\right] = 6 - \frac{1}{2} \log 20
pH=5.35\therefore pH = 5.35