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Question: The pH of 0.01 (M) KOH is 12 ; if the temperature of the given KOH solution is increased which of th...

The pH of 0.01 (M) KOH is 12 ; if the temperature of the given KOH solution is increased which of the following would occur ?

A

Both pH and pOH would remain constant

B

pH would be decreased but pOH remain constant

C

pH would be increased while pOH remain constant

D

pH would be increased while pOH would be decreased

Answer

pH would be decreased but pOH remain constant

Explanation

Solution

Since KOH is a strong electrolyte its dissociation remain unaffected, hence, [OH–] = 10–2

or pOH = 2 but on increasing temperature pKw < 14 or pH + pOH < 14

or pH < 12

Therefore pH would be decreased.