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Question: The oxidation state of sulphur in the anions \(SO_{3}^{2 -}\), \(SO_{4}^{2 -},S_{2}O_{4}^{2 -},S_{2}...

The oxidation state of sulphur in the anions SO32SO_{3}^{2 -}, SO42,S2O42,S2O62SO_{4}^{2 -},S_{2}O_{4}^{2 -},S_{2}O_{6}^{2 -} is in the order of

A

S2O42>S2O62>SO42>SO32S_{2}O_{4}^{2 -} > S_{2}O_{6}^{2 -} > SO_{4}^{2 -} > SO_{3}^{2 -}

B

S2O62>SO32>S2O42>SO42S_{2}O_{6}^{2 -} > SO_{3}^{2 -} > S_{2}O_{4}^{2 -} > SO_{4}^{2 -}

C

SO42>S2O62>SO32>S2O42SO_{4}^{2 -} > S_{2}O_{6}^{2 -} > SO_{3}^{2 -} > S_{2}O_{4}^{2 -}

D

SO32>SO42>S2O42>S2O62SO_{3}^{2 -} > SO_{4}^{2 -} > S_{2}O_{4}^{2 -} > S_{2}O_{6}^{2 -}

Answer

SO42>S2O62>SO32>S2O42SO_{4}^{2 -} > S_{2}O_{6}^{2 -} > SO_{3}^{2 -} > S_{2}O_{4}^{2 -}

Explanation

Solution

: SO32x+(6)=2x=+4SO_{3}^{2 -} \rightarrow x + ( - 6) = - 2 \Rightarrow x = + 4

SO42x+(8)=2x=+6SO_{4}^{2 -} \rightarrow x + ( - 8) = - 2 \Rightarrow x = + 6

S2O422x+(8)=2x=+3S_{2}O_{4}^{2 -} \rightarrow 2x + ( - 8) = - 2 \Rightarrow x = + 3

S2O622x+(12)=2x=+5S_{2}O_{6}^{2 -} \rightarrow 2x + ( - 12) = - 2 \Rightarrow x = + 5

Hence , SO42>S2O62>SO32>S2O42SO_{4}^{2 -} > S_{2}O_{6}^{2 -} > SO_{3}^{2 -} > S_{2}O_{4}^{2 -}