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Question

Chemistry Question on Coordination Compounds

The oxidation number of cobalt in K[Co(CO)4]K[Co(CO)_4] is

A

+1+1

B

+3+3

C

1-1

D

3-3

Answer

1-1

Explanation

Solution

We know that COCO is a neutral ligand and KK carries a charge of +1.+1. Therefore, the complex can be written as K+[Co(CO)4]K ^{+} [Co(CO)_4] ^{-} . Therefore, the oxidation number of CoCo in the given complex is 1.-1. Hence, option (iii) is correct