Question
Question: The oxidation number of \(C\) in \(HNC\) is: (A) \( + 2\) (B) \( - 3\) (C) \( + 3\) (D) \...
The oxidation number of C in HNC is:
(A) +2
(B) −3
(C) +3
(D) 0
Solution
The oxidation number of a free element is always 0.
-The oxidation number of a monatomic ion equals the charge of the ion.
-The oxidation number of H is +1, but it is -1 in when combined with less electronegative elements.
-The oxidation number of O in compounds is usually -2, but it is -1 in peroxides.
Complete step by step answer:
Oxidation state, also called oxidation number describes the degree of oxidation (loss of electrons) of an atom in a chemical compound.
Oxidation number of hydrogen is +1. As nitrogen is more electronegative than carbon so its oxidation no. is −3.
We know that net charge on the compound is zero.
Let the oxidation number of carbon is x.
1+(−3)+x=0
x=2
Hence, option A is the correct answer.
Additional information:
Oxidation numbers are typically represented by integers which can be positive, negative or zero. In some cases, the average oxidation number of an element is fraction such as 38.
For iron in magnetite (Fe3O4).
The highest known oxidation state is reported to be +9 in the tetrox iridium (IX)cation (IrO4+).
It is predicted that even a +10 oxidation state may be achievable by platinum in tetrox platinum cation (PtO42+).
The lowest oxidation state is −5, as for boron in Al3BC.
Note:
The increase in oxidation number of an atom, through a chemical reaction is known as an oxidation. A decrease in oxidation state is known as a reduction.