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Question

Chemistry Question on Chemical bonding and molecular structure

The ONOONO angle is maximum in

A

NO3NO^-_3

B

NO2NO_2

C

NO2NO^-_2

D

NO2+NO^+_2

Answer

NO2+NO^+_2

Explanation

Solution

The bond angle is maximum in NO2+(180)NO _{2}^{+}\left(180^{\circ}\right). NO3NO _{3}^{-}-In NO3,NNO _{3}^{-}, N atom undergo sp2s p^{2}-hybridisation. Each oxygen atom also has sp2s p^{2}-hybridisation. The ion has trigonal planar geometry with bond angle 120120^{\circ}. NO 22_{2}^{2-}- It has angular geometry (sp2\left(s p^{2}\right. hybridisation) due to presence of lone pair of electron on NN atom. Bond angle 116116^{\circ}. NO2N O _{2}-It has angular geometry ( sp2s p^{2} hybridisation), bond angle 134134^{\circ}. NO2+N O _{2}^{+}-Nitronium ion has linear structure (sp hybridisation) with bond angle 180180^{\circ}.