Question
Question: The \( O-H \) bond length in \( {{H}_{2}}O \) is \( x{{A}^{0}}. \) The \( O-H \) bond length in \( {...
The O−H bond length in H2O is xA0. The O−H bond length in H2O2 is:
(A) (B) x{{A}^{0}} (C) >x{{A}^{0}} (D) 2x{{A}^{0}} $
Solution
Hint : We know that the average length between the nuclei of two bound atoms in a molecule is known as bond length or bond distance in molecular geometry. It's a property of a bond between fixed-type atoms that can be transferred, despite the rest of the molecule being largely unaffected.
Complete Step By Step Answer:
As we know, the most basic form of peroxide is hydrogen peroxide oxygen-oxygen single bond. It's a colorless substance that's used in aqueous solutions to keep things clean. It is used as a disinfectant as well as a bleaching agent. In rocketry, concentrated hydrogen peroxide is used as a propellant because it is a highly reactive oxygen species. The distance between the nuclei of two chemically bound atoms in a molecule is measured by bond length. It is roughly proportional to the number of the two bonded atoms' covalent radii.
Bond length is proportional to bond order: the longer the bond, the more electrons involved in its creation. Bond length is also inversely related to bond strength and bond dissociation energy: a stronger bond would be shorter if all other variables remain constant. Half of the bond width is equal to the covalent radius in a bond between two similar atoms. It's a colorless liquid that's used in aqueous solutions to keep things safe. It is used as a disinfectant as well as a bleaching agent. In solid phase O−H bond length in H2O2 is 98.8 pm and in gaseous phase it is 95 pm. But O−H bond length in water is always 96 pm.
Therefore, the correct answer is option A.
Note :
Remember that the bond length is inversely proportional to bond order in covalent bonds; higher bond orders result in stronger bonds, which are followed by stronger forces of attraction that tie the atoms together. These powerful powers of attraction result in short bonds.