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Question

Chemistry Question on coordination compounds

The number of geometrical isomers of the complex [Co(NO2)3(NH3)3][Co(NO_2)_3(NH_3)_3] is

A

4

B

0

C

2

D

3

Answer

2

Explanation

Solution

For octahedral Ma3b3Ma_3b_ 3 complexes there are two isomers facial where the 'a' ligands occupy one face (all cis) and meridional where one of the 'a' ligands is moved so it is in the same equatorial plane as the other two 'a' ligands.