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Question

Atomic and Molecular Physics Question on Atoms

The non-relativistic Hamiltonian for a single electron atom is
H0=p22mV(r)H_0 = \frac{p^2}{2m} - V(r)
where V(r)V(r) is the Coulomb potential and mm is the mass of the electron.Considering the spin-orbit interaction term:
H=12m2c21rdVdrLSH' = \frac{1}{2m^2c^2} \frac{1}{r} \frac{dV}{dr} \overrightarrow{L} \cdot \overrightarrow{S}
added to H0H_0, which of the following statements is/are true?

A

HH' commutes with L2L^2.

B

HH' commutes with LzL_z and SzS_z.

C

For a given value of principal quantum number nn and orbital angular momentum quantum number ll, there are 2(2l+1)2(2l + 1) degenerate eigenstates of H0H_0.

D

H0H_0, L2L^2, S2S^2, LzL_z, and SzS_z have a set of simultaneous eigenstates.

Answer

HH' commutes with L2L^2.

Explanation

Solution

The correct Answers are (A):HH' commutes with L2L^2.,(C):For a given value of principal quantum number nn and orbital angular momentum quantum number ll, there are 2(2l+1)2(2l + 1) degenerate eigenstates of H0H_0. ,(D): H0H_0, L2L^2, S2S^2, LzL_z, and SzS_z have a set of simultaneous eigenstates,