Question
Atomic and Molecular Physics Question on Atoms
The non-relativistic Hamiltonian for a single electron atom is
H0=2mp2−V(r)
where V(r) is the Coulomb potential and m is the mass of the electron.Considering the spin-orbit interaction term:
H′=2m2c21r1drdVL⋅S
added to H0, which of the following statements is/are true?
H′ commutes with L2.
H′ commutes with Lz and Sz.
For a given value of principal quantum number n and orbital angular momentum quantum number l, there are 2(2l+1) degenerate eigenstates of H0.
H0, L2, S2, Lz, and Sz have a set of simultaneous eigenstates.
H′ commutes with L2.
Solution
The correct Answers are (A):H′ commutes with L2.,(C):For a given value of principal quantum number n and orbital angular momentum quantum number l, there are 2(2l+1) degenerate eigenstates of H0. ,(D): H0, L2, S2, Lz, and Sz have a set of simultaneous eigenstates,