Solveeit Logo

Question

Question: The most volatile compound among the given option is...

The most volatile compound among the given option is

A

o-nitrophenol

B

p-nitrophenol

C

m-nitrophenol

D

can't say

Answer

o-nitrophenol

Explanation

Solution

o-nitrophenol exhibits intramolecular hydrogen bonding, which reduces intermolecular forces between molecules. p-nitrophenol and m-nitrophenol primarily form intermolecular hydrogen bonds, leading to stronger intermolecular forces and molecular association. Weaker intermolecular forces in o-nitrophenol result in a lower boiling point and higher volatility compared to m- and p-nitrophenol.