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Question

Chemistry Question on coordination compounds

The most stable complex among the following is

A

K3[A1(C2O4)3]K_3[A1(C_2O_4)_3]

B

[Pt(en)2]Cl2[Pt(en)_2]Cl_2

C

[Ag(NH3)2]CI[Ag(NH_3)_2]CI

D

K2[Ni(EDTA)] K_2[Ni(EDTA)]

Answer

K2[Ni(EDTA)] K_2[Ni(EDTA)]

Explanation

Solution

In the complex K2[Ni(EDTA)]K_2[Ni(EDTA)], EDTA is a hexadentate ligand. Such a complex will be more stable than complexes formed with bidentate ligands like C2O42,(en)2C_2O^{2-}_4 \, , (en)_2 or monodentate ligand, NH3NH_3.