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Question

Chemistry Question on reaction mechanism

The most reactive to nucleophilic attack at the carbonyl group is

A

B

C

D

Answer

Explanation

Solution

The case with which a nucleophile attacks the carbonyl group depends upon the electron deficiency, i.e. the magnitude of positive charge on carbonyl group carbon. Since, among all the groups attached

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has maximum electron withdrawing effect, electron deficiency will be maximum at carbonyl carbon of acetyl chloride. Hence, acetyl chloride, i.e.

is most reactive to nucleophilic attack at carbonyl group