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Question: The molecular weight of a gas is \(40\). At \(400\text{K}\), if \(120g\) of this gas has a volume of...

The molecular weight of a gas is 4040. At 400K400\text{K}, if 120g120g of this gas has a volume of 20 litres20\text{ litres}, the pressure of the gas is?
A. 5.02 atm5.02\text{ atm}
B. 0.546 atm\text{0}\text{.546 atm}
C. 4.92 atm\text{4}\text{.92 atm}
D. 49.6 atm\text{49}\text{.6 atm}

Explanation

Solution

To solve this question, simply apply the ideal gas equation. The ideal gas equation is given by PV=nRTPV=nRT. Keep in mind that; one mole of gas is the molar mass of a gas. Use the standard temperature and pressure values to find the required answer.

Complete step by step solution:
First of all; let us have some knowledge about the ideal gas equation. So, the ideal gas equation has pressure, temperature, moles, and volume. The equation for the ideal gas is given by:
PV=nRTPV=nRT, where
P is the pressure,
V is the volume,
n is the number of moles (i.e. the amount of substance),
R is the universal gas constant (whose value is 0.0821 atm.L.mol1.K10.0821\text{ atm}\text{.L}\text{.mo}{{\text{l}}^{-1}}\text{.}{{\text{K}}^{-1}}) and
T is the temperature.
Given that,
The molecular weight of a gas is 4040and at 400K400K, the weight of the gas given is 120g120g and volume is 2020 liters. The pressure (consider as P) of the gas is to be calculated.
We know that; one mole of gas means the molar mass of the gas and equals to the ratio of weight given to that of the molecular mass of that substance.
So, here the mole of gas will be =mass givenmolecular weight of the gas=12040=3=\dfrac{\text{mass given}}{\text{molecular weight of the gas}}=\dfrac{120}{40}=3
Now by applying the ideal gas equation, we will get the pressure value as:
PV=nRTPV=nRT
Then, P=nRTVP=\dfrac{nRT}{V}
By putting the values,
P=3×0.0821×40020=4.926 atm4.92 atmP=\dfrac{3\times 0.0821\times 400}{20}=4.926\text{ atm}\cong \text{4}\text{.92 atm}
The value of pressure is 4.926 atm4.926\text{ atm}.

Hence, the correct option is C.

Note: In ideal gas related questions, the formula that is to be kept in mind is PV=nRTPV=nRT. From this single formula, other formulas can be derived. The universal gas constant that is denoted as R has different values like 0.0821 atm.L.mol1.K10.0821\text{ atm}\text{.L}\text{.mo}{{\text{l}}^{-1}}.{{\text{K}}^{-1}}, 8.314 J.mol1.K18.314\text{ J}\text{.mo}{{\text{l}}^{-1}}\text{.}{{\text{K}}^{-1}} and 1.987 cal.mol1.K1\text{1}\text{.987 cal}\text{.mo}{{\text{l}}^{-1}}\text{.}{{\text{K}}^{-1}}. The units have to be considered.