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Question

Chemistry Question on Electrochemistry

The molar conductivity for electrolytes A and B are plotted against C1/2 as shown below. Electrolytes A and B respectively are :
Graph

A
AB
Weak electrolyteWeak electrolyte
B
AB
Strong electrolytestrong electrolyte
C
AB
Weak electrolytestrong electrolyte
D
AB
Strong electrolyteWeak electrolyte
Answer
AB
Weak electrolytestrong electrolyte
Explanation

Solution

Explanation: The graph shows the variation of molar conductivity (Λm\Lambda_m) with C1/2C^{1/2}, the square root of concentration:

  1. Electrolyte A: The molar conductivity of AA increases steeply as C1/2C^{1/2} approaches 0, indicating AA is a weak electrolyte. For weak electrolytes, the molar conductivity increases significantly with dilution due to ionization.
  2. Electrolyte B: The molar conductivity of BB remains relatively constant with C1/2C^{1/2}, indicating BB is a strong electrolyte. For strong electrolytes, the variation of molar conductivity with concentration is minimal.

Therefore:

Electrolyte A → Weak electrolyte, Electrolyte B → Strong electrolyte.

Final Answer is Option (3).