Question
Chemistry Question on Electrochemistry
The molar conductivity for electrolytes A and B are plotted against C1/2 as shown below. Electrolytes A and B respectively are :
A
A | B |
---|---|
Weak electrolyte | Weak electrolyte |
B
A | B |
---|---|
Strong electrolyte | strong electrolyte |
C
A | B |
---|---|
Weak electrolyte | strong electrolyte |
D
A | B |
---|---|
Strong electrolyte | Weak electrolyte |
Answer
A | B |
---|---|
Weak electrolyte | strong electrolyte |
Explanation
Solution
Explanation: The graph shows the variation of molar conductivity (Λm) with C1/2, the square root of concentration:
- Electrolyte A: The molar conductivity of A increases steeply as C1/2 approaches 0, indicating A is a weak electrolyte. For weak electrolytes, the molar conductivity increases significantly with dilution due to ionization.
- Electrolyte B: The molar conductivity of B remains relatively constant with C1/2, indicating B is a strong electrolyte. For strong electrolytes, the variation of molar conductivity with concentration is minimal.
Therefore:
Electrolyte A → Weak electrolyte, Electrolyte B → Strong electrolyte.
Final Answer is Option (3).