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Question: The members of group 14 from tetrahalides of the type \(\mathrm { MX } _ { 4 }\) which of the follow...

The members of group 14 from tetrahalides of the type MX4\mathrm { MX } _ { 4 } which of the following halides cannot be radily hydrolysed by water?

A

CX4\mathrm { CX } _ { 4 }

B

C

D

SnX4\mathrm { SnX } _ { 4 }

Answer

CX4\mathrm { CX } _ { 4 }

Explanation

Solution

: Except carbon halides, other halides are readily hydroylsed by water. in CCl4\mathrm { CCl } _ { 4 }the central atom cannot accommodate lone pair of electrons from oxygen atom of water molecule due to absence of d – orbitals.