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Question

Chemistry Question on Electrochemistry

The mass of silver (Molar mass of Ag : 108 gmol–1 ) displaced by a quantity of electricity which displaces 5600 mL of O2 at S.T.P. will be _____ g.

Answer

The equation for the equivalent of Ag is:

Eq. of Ag=Eq. of O2\text{Eq. of Ag} = \text{Eq. of } O_2

Let x grams of silver be displaced.

x108=5.622.7×4\frac{x}{108} = \frac{5.6}{22.7} \times 4

Using the molar volume of gas at STP (22.7 L), we get:

x=106.57gx = 106.57 \, \text{g}

Thus, the answer is approximately 107 g.

Alternatively, using 22.4 L as the molar volume at STP:

x108=5.622.4×4\frac{x}{108} = \frac{5.6}{22.4} \times 4

which gives x=108gx = 108 \, \text{g}.

Explanation

Solution

The equation for the equivalent of Ag is:

Eq. of Ag=Eq. of O2\text{Eq. of Ag} = \text{Eq. of } O_2

Let x grams of silver be displaced.

x108=5.622.7×4\frac{x}{108} = \frac{5.6}{22.7} \times 4

Using the molar volume of gas at STP (22.7 L), we get:

x=106.57gx = 106.57 \, \text{g}

Thus, the answer is approximately 107 g.

Alternatively, using 22.4 L as the molar volume at STP:

x108=5.622.4×4\frac{x}{108} = \frac{5.6}{22.4} \times 4

which gives x=108gx = 108 \, \text{g}.