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Question

Chemistry Question on Colligative Properties

The mass of glucose that should be dissolved in 50g50\, g of water in order to produce the same lowering of vapour pressure as is produced by dissolving 1g1\, g of urea in the same quantity of water is

A

1 g

B

3 g

C

6 g

D

18 g

Answer

3 g

Explanation

Solution

PPsP=w1M2w2M1\frac{P-P_{s}}{P}=\frac{w_{1} M_{2}}{w_{2} M_{1}}

To produce same lowering of vapour pressure, PPsP\frac{P-P_{s}}{P} will be same for both cases.

So, W(Glucose) ×1850×180=W(urea) ×1850×60\frac{W_{\text {(Glucose) }} \times 18}{50 \times 180} =\frac{W_{\text {(urea) }} \times 18}{50 \times 60}
W(Glucose) W_{\text {(Glucose) }} = weight of glucose

W(Glucose) W_{\text {(Glucose) }} = weight of urea

or W(Glucose) ×1850×180=1×1850×60\frac{W_{\text {(Glucose) }} \times 18}{50 \times 180}=\frac{1 \times 18}{50 \times 60}
W(Glucose) =3W_{\text {(Glucose) }}=3