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Question

Chemistry Question on Quantum Mechanical Model of Atom

The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.

Answer

From de Broglie's equation,
λ=hmvλ = \frac {h}{mv}
Given,
Kinetic energy (K.E) of the electron = 3.0 × 10-25 J
Since K.E.=12mv2K.E. = \frac 12 mv^2
∴ Velocity v=2K.Emv = \sqrt {\frac {2K.E}{m}}

v=2(3.0×1025J)9.10939×1031kgv= \sqrt {\frac {2(3.0 × 10^{-25} J)}{9.10939 × 10^{-31}kg}}
v=6.5866×104v= \sqrt { 6.5866×10^4}
v=811.579 ms1v = 811.579 \ ms^{-1}
Substituting the value in the expression of λ:
λ=6.626×1034Js(9.10939×1031kg)(811.579 ms1)λ = \frac {6.626×10^{-34} Js}{(9.10939 × 10^{-31} kg) (811.579 \ ms^{-1})}
λ=8.9625×107mλ = 8.9625×10^{-7} m

Hence, the wavelength of the electron is 8.9625×107m8.9625×10^{-7} m.