Question
Chemistry Question on Electrochemistry
The limiting molar conductivities of NaI, NaNO3 and AgNO3 are 12.7, 12.0 and 13.3 mS m2 mol–1, respectively (all at 25°C). The limiting molar conductivity of AgI at this temperature is ____ mS m2 mol–1.
Answer
The limiting molar conductivity of AgI,
Λm0(AgI)=Λm0(NaI)+Λm0(AgNO3)−Λ0m(NaNO3)
Λm0(AgI)=12.7+13.3–12.0
Λm0(AgI)=26–12
Λm0(AgI)=14 mSm2mol–1
So, the answer is 14 mSm2mol–1.