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Question

Chemistry Question on Isomerism in Coordination Compounds

The IUPAC{IUPAC} name of [Co(NH3)6][Cr(C2O4)3]{[Co(NH3)6] [Cr(C2O4)3]} is

A

hexaammine cobalt (III) tris (oxalato) chromium

B

hexaammine cobalt (III) tris (oxalato) chromate (III)

C

hexaammine cobalt tris (oxalato) chromium (III)

D

hexaammine cobalt (III) chromium (III) oxalate

Answer

hexaammine cobalt (III) tris (oxalato) chromate (III)

Explanation

Solution

The complex exists as [Co(NH3)6]3+[Cr(C2O4)3]3\left[ Co \left( NH _{3}\right)_{6}\right]^{3+}\left[ Cr \left( C _{2} O _{4}\right)_{3}\right]^{3-}
and named as 'Hexaammine cobalt(III) tris(oxalato) chromate(III)
Metal having a cation complex is named first followed by anionic complex.