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Question: The isotope of carbon \(C^{14}\) has a half life of \(5730\; yrs\). If the ratio of \(C^{14}\) to \(...

The isotope of carbon C14C^{14} has a half life of 5730  yrs5730\; yrs. If the ratio of C14C^{14} to C12C^{12} is 1.3×10131.3\times 10^{-13} in a wood sample , then find activity of sample of 1  g1\;g of wood”

& A.2\times {{10}^{-12}}Bq \\\ & B.0.02Bq \\\ & C.2\times {{10}^{-10}}Bq \\\ & D.2\times {{10}^{10}}Bq \\\ \end{aligned}$$
Explanation

Solution

Radioactive decay is the spontaneous breakdown of an atomic nucleus, with emission of energy and matter. To calculate the activity, we need to find the number of nuclei which are a part of the reaction and the decay constant.

Formula used: A=λNA=\lambda N,
T12=ln2λT_{\dfrac{1}{2}}=\dfrac{ln2}{\lambda} and N=k12NAN=\dfrac{k}{12}N_{A}

Complete step by step answer:
We know that radioactive decay is the spontaneous breakdown of an atomic nucleus, with emission of energy and matter. The elements which undergo radioactive decay are generally unstable. The common radioactive decays are α,β\alpha,\beta andγ\gamma decay. These are generally found in nuclear reactions.
Also from the first law of radioactive decay, we know that N=N0eλtN=N_{0}e^{- \lambda t}, where NN is the number of nuclei after reaction, N0N_{0} is the number of nuclei before the reaction, λ\lambda is the decay constant, and tt is the time taken.
We know that half life T12T_{\dfrac{1}{2}} is given as T12=ln2λT_{\dfrac{1}{2}}=\dfrac{ln2}{\lambda}
Given that T12=5730yrT_{\dfrac{1}{2}}=5730yr
    λ=0.6935730yrs1\implies \lambda=\dfrac{0.693}{5730} yrs^{-1}
We know that the activity AA is given as A=λNA=\lambda N where NN is the number of nuclei after reaction, and λ\lambda is the decay constant.
Given that the ratio of C14C^{14} to C12C^{12} k=1.3×1013k=1.3\times 10^{-13}, then we get, N=k12NAN=\dfrac{k}{12}N_{A}, where NAN_{A} is Avogadro number. Here 1212 is taken as we compare the amount of the element C14C^{14} to 112\dfrac{1}{12} of C12C^{12}. This is a standard way of defining radioactivity.

    N=1.3×101312×6.022×1023\implies N=\dfrac{1.3\times 10^{-13}}{12}\times 6.022\times 10^{23}
    N=6.52×109\implies N=6.52\times 10^{9}
Then, A=0.6935730×365×24×3600×6.52×109=0.025BqA= \dfrac{0.693}{5730\times 365\times 24\times 3600} \times 6.52\times 10^{9}=0.025Bq

So, the correct answer is “Option B”.

Note: The SI unit of radioactive decay is becquerel (Bq) named after Henri Becquerel. One Bq is one nucleus decay of one seconds. Or in terms of curie (Cu) named after Curie, it is the amount of radiation emitted in equilibrium with one gram of pure radium isotope. Radioactivity is also defined as the amount of the element present with respect to 112\dfrac{1}{12} of C12C^{12}.