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Question: The ionisation enthalpy of hydrogen atom is 1.312 ´ 06 J mol–1. The energy required to excite the el...

The ionisation enthalpy of hydrogen atom is 1.312 ´ 06 J mol–1. The energy required to excite the electron in the atom from n1 = 1 to n2 = 2 is

A

8.51 ´ 105 J mol–1

B

6.56 ´ 105 J mol–1

C

7.56 ´ 105 J mol–1

D

9.84 ´ 105 J mol–1

Answer

9.84 ´ 105 J mol–1

Explanation

Solution

I.E. = 1.312 × 106 J mol–1

The energy required to excite the electron in the atom from n1 = 1 to n = 2.

= 1.312 × 106 [114]\left\lbrack 1 - \frac{1}{4} \right\rbrack

= 1.312 × 106 × 34\frac{3}{4}

= 9.84 × 105 J mol–1