Question
Question: The hybridization of \(N,C\) and \(O\) shown in the following compound respectively are: 
A.sp2,sp,sp2
B.sp2,sp2,sp2
C.sp2,sp,sp
D.sp,sp,sp2
Solution
Hybridization is characterized as the concept of mixing two atomic orbitals to give a degenerated new form of orbitals with the same energy levels. The combining of atomic orbitals to form new orbitals of different energies and shapes than the initial orbitals is hybridization.
Complete answer:
Orbital hybridization is the concept of mixing atomic orbitals to form new hybrid orbitals (with different energies, shapes, etc., then the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory.
Hybridisation Nσ+NL.p.
sp 2
sp2 3
sp3 4
sp3d 5
Nσ+NL.p.=3,2,3 for N,C and O respectively.
So, the given compound has sp2,so,,sp2hybridization for N,C, and O atoms respectively.
So, the correct answer is (A) sp2,sp,sp2
Additional information:
Hybridization of s and p orbitals to form effective spX hybrids requires that they have comparable radial extent. While 2p orbitals are on average less than 10% larger than 2s, in part attributable to the lack of a radial node in 2p orbitals, 3p orbitals which have one radial node, exceed the 3s orbitals by 20−33%.The difference in the extent of s and p orbitals increases further down a group. The hybridisation of atoms in chemical bonds can be analyzed by considering localized molecular orbitals.
Note:
Hybridisation helps to explain molecule shape, since the angles between bonds are approximately equal to the angles between hybrid orbitals. In contrast to valence shell electron-pair repulsion (VSEPR) theory, which can be used to predict molecular geometry based on empirical rules rather than on valence-bond or orbital theories.
