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Question: The hybridisation of [ Co F6] 3– and [ Co (C2O4)3 ]3 – are :...

The hybridisation of [ Co F6] 3– and [ Co (C2O4)3 ]3 – are :

A

Both sp3d2

B

Both d2sp3

C

sp3d2 and d2sp3 respectively

D

d2sp3 and sp3d2 respectively

Answer

sp3d2 and d2sp3 respectively

Explanation

Solution

In both complexes the oxidation state of cobalt is +3 with 3d6 configuration. Except [CoF6]3–, all other complexes of cobalt with weak field and strong field ligands are inner orbital complexes and diamagnetic because of higher CFSE.