Question
Chemistry Question on Chemical Kinetics
The half life period of a radio active element is 30 days, after 90 days the following quantity will be left
A
81
B
41
C
21
D
61
Answer
81
Explanation
Solution
All radioactive elements follow first order kinetics, Given, t1/2=30 days ∴ Rate constant, k=t1/20.693=300.693 days −1 Now, as we know for first order reaction, k=t2.303loga−xa Here, t=90 days, a=1 ∴300.693=902.303log1−x1 or 0.9027=log1−x1 Or 8=1−x1 ∴1−x=81 N=2nN0 (where, n= number of half-life, N0= initial mass of radioactive element, N= final mass) ∴N=23N0 N=8N0