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Question

Chemistry Question on Chemical Kinetics

The half-life of a radioactive element is 10 hours. How much will be left after 4 hours in 1 g atom sample?

A

45.6×102145.6\times10^{21} atoms

B

45.6×102345.6\times10^{23} atoms

C

45.6×102445.6\times10^{24} atoms

D

45.6×102045.6\times10^{20} atoms

Answer

45.6×102345.6\times10^{23} atoms

Explanation

Solution

k=0.693t1/2=0.69310hr1k=\frac{0.693}{t_{1 / 2}}=\frac{0.693}{10} hr ^{-1} k=2.3034log1×6.023×1023Nk=\frac{2.303}{4} \log \frac{1 \times 6.023 \times 10^{23}}{N} (1g\left(\because 1 g\right. atom =6.023×1023=6.023 \times 10^{23} atom ))
0.69310=2.3034log6.023×1023N\Rightarrow \frac{0.693}{10}=\frac{2.303}{4} \log \frac{6.023 \times 10^{23}}{N}
or
log6.023×1023N=0.12036\log \frac{6.023 \times 10^{23}}{N}=0.12036 6.023×1023N=1.319\frac{6.023 \times 10^{23}}{N}=1.319
N=4.56×1023\therefore N=4.56 \times 10^{23} atom.