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Question: The half-life of \[{}_{38}^{90}Sr\] is 28 years. What is the disintegration rate of 15mg of this iso...

The half-life of 3890Sr{}_{38}^{90}Sr is 28 years. What is the disintegration rate of 15mg of this isotope?

Explanation

Solution

To find the disintegration rate of 15mg 3890Sr{}_{38}^{90}Sr isotope first of all we have to calculate the number of radioactive nuclei present in the 15mg of 3890Sr{}_{38}^{90}Sr and the rate constant for the disintegration. Then, we will go the formula: (dNdt)=λN\left( { - \dfrac{{dN}}{{dt}}} \right) = \lambda N, where (dNdt)\left( { - \dfrac{{dN}}{{dt}}} \right) represent the rate of decay or disintegration rate, λ\lambda is the rate constant and NN is the number of radioactive nuclei present at the time tt. Finally, we will calculate the value of λN\lambda N in order to get the required disintegration rate. All the calculations that we will use to solve the problems are taken in the SI system.

Complete step-by-step answer:
To find the required value for the disintegration rate of 15mg of 3890Sr{}_{38}^{90}Sr:-
The formula used is: (dNdt)=λN\left( { - \dfrac{{dN}}{{dt}}} \right) = \lambda N……………….. (i) (Where λ\lambda is the rate constant and NN is the number of radioactive nuclei present at the time tt.)
Given:-
t12=28{t_{\dfrac{1}{2}}} = 28 Years
=28×365×24×3600 s= 28 \times 365 \times 24 \times 3600{\text{ s}}
t12=8.83×108 s\Rightarrow {t_{\dfrac{1}{2}}} = 8.83 \times {10^8}{\text{ s}}…………….. (ii)
Mass of 3890Sr=15mg{}_{38}^{90}Sr = 15mg
=15×103g= 15 \times {10^{ - 3}}g,
Since the atomic mass of 3890Sr=87.62 g/mol{}_{38}^{90}Sr = 87.62{\text{ }}g/mol
As we know that 87.62 g/mol87.62{\text{ }}g/mol of 3890Sr{}_{38}^{90}Sr containing 6.022×10236.022 \times {10^{23}} atoms, So
Number of radioactive nuclei (N) present in 15mg of 3890Sr=(6.022×1023×15×10387.62 ){}_{38}^{90}Sr = \left( {\dfrac{{6.022 \times {{10}^{23}} \times 15 \times {{10}^{ - 3}}}}{{87.62{\text{ }}}}} \right)
=1.03×1020= 1.03 \times {10^{20}}
Thus, N=1.03×1020N = 1.03 \times {10^{20}}
Calculating the rate constant λ\lambda :
λ=0.693t12\lambda = \dfrac{{0.693}}{{{t_{\dfrac{1}{2}}}}} disintegration/s
=0.6938.83×108= \dfrac{{0.693}}{{8.83 \times {{10}^8}}} disintegration/s
Substitute the value of λ\lambda and NN in equation(i), we get
Rate of disintegration (dNdt)=(0.6938.83×108×1.03×1020)\left( { - \dfrac{{dN}}{{dt}}} \right) = \left( {\dfrac{{0.693}}{{8.83 \times {{10}^8}}} \times 1.03 \times {{10}^{20}}} \right) disintegration/s
=8.08×1010= 8.08 \times {10^{10}} disintegration/s
Hence, the required disintegration rate of 15mg of 3890Sr=8.08×1010{}_{38}^{90}Sr = 8.08 \times {10^{10}} disintegration/s.

Note: In order to master these kinds of problems we have to keep practicing a lot of conceptual questions on radioactive disintegration law. Students often confuse term activity and rate of disintegration so do not get confused with that they both are identical although at many radioactive reactions we generally use the term activity. One should also care about the data given in the problem that must be used in the SI system while solving the problem.