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Question

Chemistry Question on Chemical bonding and molecular structure

The ground state magnetic property of B2B_2 and C2C_2 molecules will be

A

B2B_2 paramagnetic and C2C_2 diamagnetic

B

B2B_2 diamagnetic and C2C_2 paramagnetic

C

Both are diamagnetic

D

Both are paramagnetic

Answer

B2B_2 paramagnetic and C2C_2 diamagnetic

Explanation

Solution

According to molecular orbital theory, outer configuration for
[C2]=C12πpx2=πpy2\left[ C _{2}\right]= C _{12} \rightarrow \pi p_{x}{ }^{2}=\pi p_{y}{ }^{2}
Thus, is diamagnetic in nature.
[B2]=B10>πpx1=πpy1\left[ B _{2}\right]= B _{10}->\pi p_{x}^{1}=\pi p_{y}^{1}
Thus, is paramagnetic in nature.