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Question: The graph between stopping potential ($V_0$) versus frequency ($\nu$) of the light used in an experi...

The graph between stopping potential (V0V_0) versus frequency (ν\nu) of the light used in an experiment of photoelectric effect is as shown in figure. Work function of the metal surface is

A

0.212 eV

B

0.207 eV

C

0.414 eV

D

0.428 eV

Answer

0.414 eV

Explanation

Solution

The relationship between stopping potential (V0V_0) and frequency (ν\nu) in the photoelectric effect is given by Einstein's photoelectric equation:

hν=ϕ+Kmaxh\nu = \phi + K_{max}

where hh is Planck's constant, ϕ\phi is the work function, and KmaxK_{max} is the maximum kinetic energy of the emitted photoelectrons. The maximum kinetic energy is also related to the stopping potential (V0V_0) by:

Kmax=eV0K_{max} = eV_0

where ee is the elementary charge.

Substituting KmaxK_{max} into the photoelectric equation:

hν=ϕ+eV0h\nu = \phi + eV_0

Rearranging the equation to express V0V_0:

eV0=hνϕeV_0 = h\nu - \phi V0=(he)ν(ϕe)V_0 = \left(\frac{h}{e}\right)\nu - \left(\frac{\phi}{e}\right)

This equation is in the form of a straight line, y=mx+cy = mx + c, where:

  • y=V0y = V_0 (stopping potential)
  • x=νx = \nu (frequency)
  • The slope m=hem = \frac{h}{e}
  • The y-intercept c=ϕec = -\frac{\phi}{e}

From the graph, we can determine the work function (ϕ\phi) using the threshold frequency (ν0\nu_0). The threshold frequency (ν0\nu_0) is the minimum frequency of incident light required for photoemission to occur. At this frequency, the stopping potential (V0V_0) is zero.

From the photoelectric equation, when V0=0V_0 = 0:

hν0=ϕh\nu_0 = \phi

The graph shows that the line intersects the frequency axis (where V0=0V_0 = 0) at ν=1×1014\nu = 1 \times 10^{14} Hz. So, the threshold frequency ν0=1×1014\nu_0 = 1 \times 10^{14} Hz.

Now, we can calculate the work function:

ϕ=hν0\phi = h\nu_0

Using Planck's constant h=6.626×1034h = 6.626 \times 10^{-34} J s:

ϕ=(6.626×1034 J s)×(1×1014 Hz)\phi = (6.626 \times 10^{-34} \text{ J s}) \times (1 \times 10^{14} \text{ Hz}) ϕ=6.626×1020\phi = 6.626 \times 10^{-20} J

To express the work function in electron volts (eV), we divide by the elementary charge e=1.602×1019e = 1.602 \times 10^{-19} J/eV:

ϕ=6.626×1020 J1.602×1019 J/eV\phi = \frac{6.626 \times 10^{-20} \text{ J}}{1.602 \times 10^{-19} \text{ J/eV}} ϕ0.4136 eV\phi \approx 0.4136 \text{ eV}

Rounding to three significant figures, ϕ0.414 eV\phi \approx 0.414 \text{ eV}.