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Question

Question: The general formula of carboxylic acids is: A. \({{C}_{n}}{{H}_{n}}COOH\) B. \({{C}_{n}}{{H}_{2...

The general formula of carboxylic acids is:
A. CnHnCOOH{{C}_{n}}{{H}_{n}}COOH
B. CnH2nCOOH{{C}_{n}}{{H}_{2n}}COOH
C. CnHn2COOH{{C}_{n}}{{H}_{n-2}}COOH
D. CnH2n+1COOH{{C}_{n}}{{H}_{2n+1}}COOH

Explanation

Solution

The general formula of the compounds is nothing but it represents the number of particular atoms present in the respective chemical. The general formula of alkanes is CnH2n+2{{C}_{n}}{{H}_{2n+2}} . Means in alkanes ‘n’ number of carbons and ‘2n+2’ number of hydrogens are present.

Complete answer:
- In the question it is given that the general formula of carboxylic acid is.
- We have to find which option is correct for the general formula of carboxylic acid.
- Carboxylic acid is one of the functional groups and which can be represented as –COOH.
- For every organic molecule there is a general formula to represent the number of carbon atoms, hydrogen atoms and oxygen atoms present in it.
- Carboxylic acid also has a general formula and it is CnH2n+1COOH{{C}_{n}}{{H}_{2n+1}}COOH .
- Means in carboxylic acids if it contains an ‘n’ number of carbons then it will have n+1 hydrogens other than the functional group –COOH.
- Therefore the general formula of carboxylic acid is CnH2n+1COOH{{C}_{n}}{{H}_{2n+1}}COOH.

- So, the correct option is D.

Note: Take an example of acetic acid. The molecular formula of acetic acid is CH3COOHC{{H}_{3}}COOH . Now compare the molecular formula of acetic with the general formula of acetic acid.
If we take n = 1inCnH2n+1COOH{{C}_{n}}{{H}_{2n+1}}COOH, then we will get CH3COOHC{{H}_{3}}COOH (ethanoic acid).
If we take n = 2 in CnH2n+1COOH{{C}_{n}}{{H}_{2n+1}}COOH , then we will get C2H5COOH{{C}_{2}}{{H}_{5}}COOH (propionic acid).
If we take n = 3 in CnH2n+1COOH{{C}_{n}}{{H}_{2n+1}}COOH , then we will get C3H7COOH{{C}_{3}}{{H}_{7}}COOH (butanoic acid).