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Question: The following sets of values for \(C_{V}\) and \(C_{P}\) of a gas has been reported by different stu...

The following sets of values for CVC_{V} and CPC_{P} of a gas has been reported by different students. The units are cal/gm-mole-K. Which of these sets is most reliable

A

Cv=3,Cp=5C_{v} = 3,C_{p} = 5

B

CV=4,CP=6C_{V} = 4,C_{P} = 6

C

Cv=3,Cp=2C_{v} = 3,C_{p} = 2

D

CV=3,CP=4.2C_{V} = 3,C_{P} = 4.2

Answer

Cv=3,Cp=5C_{v} = 3,C_{p} = 5

Explanation

Solution

CPCV=R=2.calgmmolKC_{P} - C_{V} = R = 2.\frac{cal}{gm - mol - K} Which is correct for option (1) and (2). Further the ratio CPCV(=γ)\frac{C_{P}}{C_{V}}( = \gamma) should equal to some standard value corresponding to that of either, mono, di, or triatomic gases. From this point of view option (1) is correct because (CPCV)mono=53\left( \frac{C_{P}}{C_{V}} \right)_{mono} = \frac{5}{3}