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Question

Chemistry Question on Order of Reaction

The following graph shows how (t1/2)(t_{1/2}) a (half life) of a reactant R changes with the initial reactant concentration a0a_0. The order of the reaction will be

A

0

B

1

C

2

D

3

Answer

2

Explanation

Solution

For second order reaction,

It can be represented as : dxdt=Kx2-\frac{dx}{dt}=Kx^{2}
1[a]=1[a0]+Kt;Kt1/2=1[a0]\frac{1}{\left[a\right]}=\frac{1}{\left[a_{0}'\right]}+Kt; Kt_{1/2}=\frac{1}{\left[a_{0}'\right]}
half-life (t1/2)=1K[a0]\left(t_{1/2}\right)=\frac{1}{K\left[a_{0}'\right]}
So, graph of t1/2t_{1/2} and 1a0\frac{1}{a_{0}}, is linear.