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Question

Chemistry Question on Bohr’s Model for Hydrogen Atom

The first line of the Lyman series in a hydrogen spectrum has a wavelength of 1210??.Thecorrespondinglineofahydrogenlikeatomof1210 ??. The corresponding line of a hydrogen- like atom of Z = 11$ is equal to

A

$4000 ??

B

$100 ??

C

$40 ??

D

$10 ??

Answer

$10 ??

Explanation

Solution

For first line of Lyman series n1=1,n2=2n_1 = 1, n_2 = 2 1λ=Z2R34\therefore \frac{1}{\lambda} = Z^2 R \frac{3}{4} In the case of hydrogen atom, Z=1,1λ=R34Z = 1, \frac{1}{\lambda} = R{\frac{3}{4}} For hydrogen-like atom, Z=11,1λ=121R34Z = 11, \frac{1}{\lambda'} = 121 R\frac{3}{4} λλ=3R4×4121R×3\Rightarrow \frac{\lambda'}{\lambda} = \frac{3R}{4} \times \frac{4}{121R \times 3} λ=λ121\Rightarrow \lambda' = \frac{\lambda}{121} $= \frac{1210}{121} = 10,??