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Question: The first line of the Lyman series in a hydrogen spectrum has a wavelength of 1210 Å. The correspond...

The first line of the Lyman series in a hydrogen spectrum has a wavelength of 1210 Å. The corresponding line of a hydrogen-like atom of Z = 11 is equal to

A

4000 Å

B

100 Å

C

40 Å

D

10 Å

Answer

10 Å

Explanation

Solution

By Bohr’s formula

1λ=Z2R[1n121n22]\frac{1}{\lambda} = Z^{2}R\left\lbrack \frac{1}{n_{1}^{2}} - \frac{1}{n_{2}^{2}} \right\rbrack

For first line of Lyman series n1=1,n2=2n_{1} = 1,n_{2} = 2

1λ=Z2R34\therefore\frac{1}{\lambda} = Z^{2}R\frac{3}{4}

In the case of hydrogen atom Z = 1

For hydrogen like atom Z=11Z = 11

1λ=121R34λλ;=3R4×4121R×3=1121\frac{1}{\lambda'} = 121R\frac{3}{4} \Rightarrow \frac{\lambda'}{\lambda;} = \frac{3R}{4} \times \frac{4}{121R \times 3} = \frac{1}{121}

λ=λ121=1210121=10A˚\lambda' = \frac{\lambda}{121} = \frac{1210}{121} = 10Å