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Question

Chemistry Question on Classification of elements & periodicity in properties

The first ionisation potential (in eV) of Be and B, respectively are

A

8.29, 9.32

B

9.32, 9.32

C

8.29, 8.29

D

9.32, 8.29

Answer

9.32, 8.29

Explanation

Solution

First ionisation potential of Be is greater than
boron due to stable configuration
4Be=1s2,2s2\, \, \, \, \, \, \, \, \, \, _4 Be =1s^2 , 2s^2
5B=1s2,2s22p1\, \, \, \, \, \, \, \, \, \, _5 B=1s^2,2s^2 2p^1
Order of attraction of electrons towards nucleus is 2s >2p, so more amount of energy is required to remove the electron from 2 s orbital in comparison to 2p orbital. So, ionisation potential of Be is 9.32 eV and B is 8.29 eV