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Question

Question: The equivalent weight of \(K_{2}Cr_{2}O_{7}\) in acidic medium....

The equivalent weight of K2Cr2O7K_{2}Cr_{2}O_{7} in acidic medium.

A

294

B

298

C

49

D

50

Answer

49

Explanation

Solution

K2Cr2O7+3H2SO4K2SO4+Cr2(SO4)3+3(O)+3H2K_{2}Cr_{2}O_{7} + 3H_{2}SO_{4} \rightarrow K_{2}SO_{4} + Cr_{2}(SO_{4})_{3} + 3(O) + 3H_{2}

No. of electrons lossed = 12 – 6 = 6

∴ Equivalent weight = M6=2946=49.\frac{M}{6} = \frac{294}{6} = 49.