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Question

Chemistry Question on Solutions

The equivalent weight of H3PO2H _{3} PO _{2}, when it disproportionates into PH3PH _{3} and H3PO3H _{3} PO _{3} is

A

82

B

61.5

C

41

D

20.5

Answer

61.5

Explanation

Solution

The reaction can be written as Molecular weight of H3PO2H_{3} PO _{2} =3+31+48=82=3+31+48=82 Equivalent weight =824+822=61.5=\frac{82}{4}+\frac{82}{2}=61.5