Solveeit Logo

Question

Chemistry Question on Spontaneity

The entropy change involved in the isothermal reversible expansion of 22 moles of an ideal gas from a volume of 10dm310\, dm ^{3} at 27C27^{\circ} C is to a volume of 100dm3100\, dm ^{3}

A

42.3Jmol1K142.3\, J\, mol ^{-1} K ^{-1}

B

38.3Jmol1K138.3\, J\, mol ^{-1} K ^{-1}

C

35.8Jmol1K135.8\, J\, mol ^{-1} K ^{-1}

D

32.3Jmol1K132.3\, J\, mol ^{-1} K ^{-1}

Answer

38.3Jmol1K138.3\, J\, mol ^{-1} K ^{-1}

Explanation

Solution

ΔS=2.303nlogV2V1\Delta S=2.303\, n\,\log \frac{V_{2}}{V_{1}} ΔS=2.303×2×8.314×log10010\Delta S=2.303 \times 2 \times 8.314 \times \log \frac{100}{10} ΛS=38.3Jmol1K1\Lambda S=38.3\, J\, mol ^{-1} K ^{-1}