Solveeit Logo

Question

Chemistry Question on Thermodynamics

The enthalpy change for the conversion of 12Cl2(g)\frac{1}{2} Cl_2(g) to Cl(aq)Cl^{-}(aq) is (-)_____________ KJmol1KJ mol^{-1} (Nearest integer)
Given : Δdis HCl2(g)=240kJmol1\Delta_{\text {dis }} H _{ Cl _{2( g )}}^{\ominus}=240\, kJ \,mol ^{-1}, ΔegHCl=350kJmol1\Delta_{ eg } H _{ Cl }^{\ominus}=-350\, kJ \,mol ^{-1}, Δhyd HθCl(g)=380kJmol1\Delta_{\text {hyd }} H ^\theta Cl _{( g )}^{-}=-380 \,kJ \,mol ^{-1}

Answer

12Cl2(g)Cl(g)Cl(g)Cl(aq.)\frac{1}{2}​Cl_{2(g)}​→Cl_{(g)}​→Cl_{(g)}^{−}​→Cl_{(aq.)}^−​
ΔH=12×240+(350)+(380)ΔH\degree=\frac{1}{2}​\times240+(−350)+(−380)
=610=−610

The correct answer is -610