Solveeit Logo

Question

Chemistry Question on subshell electronic configuration

The energy of an electron in the ground state (n=1) for He+ ion is -xJ, then that for an electron in n=2 state for Be3+ ion in J is:

A

-x

B

x9-\frac{x}{9}

C

-4x

D

49x-\frac{4}{9}x

Answer

-x

Explanation

Solution

The energy of an electron in a hydrogen-like atom is given by:
En=13.6Z2n2eVE_n = -\frac{13.6Z^2}{n^2} \, eV,
where ZZ is the atomic number and nn is the energy level.
For
He+He^+, Z=2Z = 2, and for
Be3+Be^{3+}, Z=4Z = 4.
The ratio of energies in the ground state and n=2n = 2 for Be3+Be^{3+} gives:
EE=x1=x\frac{E}{E} = \frac{x}{1} = -x.