Question
Physics Question on band theory of solids
The energy gaps (Eg) between valence band and conduction band for diamond, silicon and germanium are in the order
A
Eg (diamond) >Eg (silicon) >Eg (germanium)
B
Eg (diamond) <Eg (silicon) <Eg (germanium)
C
Eg (diamond) =Eg (silicon) =Eg (germanium)
D
Eg (diamond) >Eg (germanium) >Eg (silicon)
Answer
Eg (diamond) >Eg (silicon) >Eg (germanium)
Explanation
Solution
The energy gaps (Eg) between valence band and conduction band for diamond, silicon and germanium are in the order Eg (diamond) >Eg (silicon) >Eg (germanium) Because diamond is an insulator and non-metallic character decreases down the group.