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Question: The electronic configuration of Cu(II) is \(3d^{9}\) whereas that of Cu(I) is \(3d^{10}\)which of th...

The electronic configuration of Cu(II) is 3d93d^{9} whereas that of Cu(I) is 3d103d^{10}which of the following is correct?

A

Cu(II) is more stable.

B

Cu (II) is less stable

C

Cu(I) and Cu(II) are equally stable

D

Stability of Cu(I) and Cu(II) depends on nature of copper salts.

Answer

Cu(II) is more stable.

Explanation

Solution

Standard electrode potential of Cu2+Cu^{2 +} is high (0.52V0.52V) as compared toCu2+(0.34V)Cu^{2 +}(0.34V), hence Cu+Cu^{+}is reduced more easily and is less stable than Cu2+Cu^{2 +}