Question
Question: The electromeric effect in organic compounds is a: A. Temporary effect B. Permanent effect C. ...
The electromeric effect in organic compounds is a:
A. Temporary effect
B. Permanent effect
C. Temporary or permanent effect
D. All of the above
Solution
The complete transfer of shared pi electrons in multiple bonds to other compounds in the presence of a reagent is called electromeric effect. Nothing but the movement of electrons from one compound having pi electrons to another atom in a different compound in the presence of a reagent.
Complete step by step answer:
- Electromeric effect can be represented with a symbol E.
- We can observe electromeric effects in organic compounds containing multiple bonds.
- There are two types of electromeric effects. +E and –E effect.
- In +E effect the pi electrons transfer towards attacking reagent and in –E effect the pi electrons transfer away from attacking reagent.
- Means in the presence of attacking reagent only +E or –E effects take place.
- Therefore the electromeric effect is a temporary effect.
So, the correct option is A.
Additional information:
- An example for +E effect is as follows.
- We can see clearly that in the above reaction pi electrons are transferred from one molecule to another because of the presence of hydrogen ions.
- An example for –E effect is as follows.
- We can see clearly that the transfer of electrons towards the multiple bond in the presence of an external reagent.
Note: For suppose if there is no external reagent then there is no electromeric effect. Means external reagents only play a big role in electromeric effect whether it is +E effect or –Affect. Electromeric effect will occur in the molecules containing double or triple bonds.