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Question

Chemistry Question on Werner’s Theory of Coordination Compounds

The effective atomic number of cobalt in the complex [Co(NH3)6]3+[Co(NH_3)_6]^{3+} is

A

36

B

24

C

33

D

30

Answer

36

Explanation

Solution

The coordination number of the metal is 6 and the oxidation state of the metal is +3
EAN = at. no. of central atom - oxidation state +2 (coordination number of the metal)
=273+2(6)= 27 -3 + 2(6)
=273+12=36= 27 -3 +12 = 36

So, the correct answer is (A): 36