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Question: The effect of temperature on equilibrium constant is expressed as (T2\> T1) log K2 / \(\mathrm { K ...

The effect of temperature on equilibrium constant is expressed as (T2> T1)

log K2 / K1ΔH2.303[1 T21 T1]\mathrm { K } _ { 1 } \frac { - \Delta \mathrm { H } } { 2.303 } \left[ \frac { 1 } { \mathrm {~T} _ { 2 } } - \frac { 1 } { \mathrm {~T} _ { 1 } } \right]. For endothermic

reaction false statement is

A

= positive

B

Δ\DeltaH = positive

C

log K2> log K1

D

K2> K1

Answer

= positive

Explanation

Solution

log K2 / logK1=ΔH2.303[1 T21 T1]= \frac { - \Delta \mathrm { H } } { 2.303 } \left[ \frac { 1 } { \mathrm {~T} _ { 2 } } - \frac { 1 } { \mathrm {~T} _ { 1 } } \right]

Δ\DeltaH = Positive