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Question

Chemistry Question on Unit Cells

The edge length of a fccfcc ionic crystal is 508 pm. If the radius of cation is 110 pm, the radius of anion will be

A

398 pm

B

288 pm

C

144 pm

D

618 pm

Answer

144 pm

Explanation

Solution

For ionic compounds,
Edge length (a)=2(r++r)(a) = 2(r_+ + r_-)
508=2(110+r)508 = 2(110 + r_-)
508=220+2r508 = 220 + 2r_-
2r=508220=288pm2r- = 508 - 220 = { 288\, pm}
r=144pmr_- = {144 \,pm}