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Question

Chemistry Question on Inorganic chemistry

The difference in the 'spin-only' magnetic moment values of KMnO4\text{KMnO}_4 and the manganese product formed during titration of KMnO4\text{KMnO}_4 against oxalic acid in acidic medium is ______ BM (nearest integer).

Answer

Spin-only magnetic moment of Mn in KMnO4_4:
μ=0\mu = 0
Spin-only magnetic moment of the manganese product formed during titration of KMnO4_4 against oxalic acid in acidic medium:
μ=6BM\mu = 6 \, \text{BM}
Difference in magnetic moments:
60=6BM6 - 0 = 6 \, \text{BM}

Explanation

Solution

Spin-only magnetic moment of Mn in KMnO4_4:
μ=0\mu = 0
Spin-only magnetic moment of the manganese product formed during titration of KMnO4_4 against oxalic acid in acidic medium:
μ=6BM\mu = 6 \, \text{BM}
Difference in magnetic moments:
60=6BM6 - 0 = 6 \, \text{BM}