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Question: The density of solid argon (Ar = 40 g/mol) is 1.68 g/mL at 40 K. If the argon atom is assumed to be ...

The density of solid argon (Ar = 40 g/mol) is 1.68 g/mL at 40 K. If the argon atom is assumed to be a sphere of radius = 1.50 × 10–8 cm, what % of solid Ar is apparently empty space?

A

35.64

B

64.36

C

74%

D

None of these

Answer

64.36

Explanation

Solution

Vol. of all atoms in 1.68 gm

argon =1.6840×NA×43×π×(1.5×108)3\frac{1.68}{40} \times N_{A} \times \frac{4}{3} \times \pi \times (1.5 \times 10^{–8})^{3} = 0.3564

vol. of solid argon = 1 cm3

% empty space = (1 – 0.3564) × 100 = 64.36