Question
Question: The degree of ionization of a \(0.1M\) bromoacetic acid solution is 0.132. Calculate the \(pH\) of t...
The degree of ionization of a 0.1M bromoacetic acid solution is 0.132. Calculate the pH of the solution and the pKa , of a bromoacetic acid.
pH of solution is = 1.88
pKa of bromo acetic acid = 2.69
Solution
pH is a measure of hydrogen ion concentration, [H+] ,in an aqueous (water) solution. The pH scale ranges from 0−14 . A low pH value indicates acidity, a pH of 7 is neutral, and a high pH value indicates alkalinity.
The formulas to calculate pH is:
pH=−log[H+]
At 250C :
pH+pOH=14
Ka | pKa |
---|---|
It is the acid dissociation constant. | It is the −log of this constant. |
Describes the degree of ionization. | Also describes the degree of ionisation. |
True indicator of acid strength.Reason: Addition of water does not change the equilibrium. | True indicator of acid strength.Reason: Addition of water does not change the equilibrium. |
The acid dissociation constants are usually expressed in terms of l−1mol .
Acids and bases dissociate according to general equations:
HA+H2O→A−+H3O+
Ka=[HA][H+][A−]
pKa=−logKa
At half the equivalence point,
pH=pKa pH=pKa=−logK
Complete step by step answer:
CH2BrCOOH→CH2BrCOO−+H+
Initial concentration | C | 0 | 0 |
---|---|---|---|
Concentration at equilibrium | C−Cα | Cα | Cα |
So, the acid dissociation constant will be:
Ka=C(1−α)Cα×Cα⇒1−αCα2≃Cα2
⇒0.1×0.132 ⇒1.74×10−3 pKa=−log(1.74×10−3) ⇒2.76
From the above values, we can find the concentration of hydrogen ion as:
[H+]=Cα⇒0.1×0.132 ⇒1.32×10−2M
So, the final calculation of pH will be:
pH=−log(1.32×10−2) ⇒1.88
Note:
A large Ka value indicates a strong acid because it means the acid is largely dissociated into its ions. A large Ka value also means the formation of products in the reaction is favored. A small Ka value means little of the acid dissociates, so you have a weak acid. The Ka value for most weak acids ranges from 10−2−10−14 .
The pKa gives the same information, just in a different way. The smaller the value of pKa , the stronger the acid. Weak acids have a pKa ranging from 2−14
Another important point is pI .This is the isoelectric point. It is at which protein molecule is electrically neutral that is having no net electric.